Fermi level modulation of boron nitride nanosheets by vacancy driven compressive strain
نویسندگان
چکیده
The compressive strain induced work function modulation in boron nitride nanosheets (BNNS) has been studied. arose due to the irradiation of 30 keV Au beam on thin films BNNS. Before BNNS was characterized by Raman spectroscopy, UV-Vis where using Tauc plot bandgap chemically synthesized from commercial hBN powder calculated as well layer numbers also quantified an empirical relation exploiting full width at half maxima (FWHM) peak Scanning Electron Microscopy (SEM) images were taken like structure pristine sample is visible and irradiation-induced changes terms irregular dots samples witnessed. X-Ray Diffraction (XRD) used characterize corresponding (002) plane depicted shifting higher angle which indicates visible. Finally, possible explanation formation discussed SRIM-2013 MC simulations. We've explained that vacancy induces materials lower (WF). Kelvin Probe (SKPM) map surface BNNS, it turned out WF lowers with increasing dose ions. value values results are qualitatively agreeing XRD results.
منابع مشابه
Biaxial Compressive Strain Engineering in Graphene/Boron Nitride Heterostructures
Strain engineered graphene has been predicted to show many interesting physics and device applications. Here we study biaxial compressive strain in graphene/hexagonal boron nitride heterostructures after thermal cycling to high temperatures likely due to their thermal expansion coefficient mismatch. The appearance of sub-micron self-supporting bubbles indicates that the strain is spatially inho...
متن کاملTaming interfacial electronic properties of platinum nanoparticles on vacancy-abundant boron nitride nanosheets for enhanced catalysis
Taming interfacial electronic effects on Pt nanoparticles modulated by their concomitants has emerged as an intriguing approach to optimize Pt catalytic performance. Here, we report Pt nanoparticles assembled on vacancy-abundant hexagonal boron nitride nanosheets and their use as a model catalyst to embrace an interfacial electronic effect on Pt induced by the nanosheets with N-vacancies and B-...
متن کاملMechanical properties of polycrystalline boron-nitride nanosheets
The first molecular dynamics (MD) study was conducted to explore mechanical-failure response of ultrafine grained single-layer boron-nitride films. We used MD simulations to construct relatively large molecular models of polycrystalline structures with random grain configurations. By applying uniaxial tensile loading, we then studied the grain size effect on the mechanical response of polycryst...
متن کاملOxygen radical functionalization of boron nitride nanosheets.
The covalent chemical functionalization of exfoliated hexagonal boron-nitride nanosheets (BNNSs) is achieved by the solution-phase oxygen radical functionalization of boron atoms in the h-BN lattice. This involves a two-step procedure to initially covalently graft alkoxy groups to boron atoms and the subsequent hydrolytic defunctionalization of the groups to yield hydroxyl-functionalized BNNSs ...
متن کاملCovalently functionalized hexagonal boron nitride nanosheets by nitrene addition.
The covalent functionalization of exfoliated hexagonal boron nitride (h-BN) nanosheets by nitrene addition is described. Integration of functionalized h-BN nanosheets within a polycarbonate matrix is demonstrated and was found to afford significant increases in mechanical properties. This integration methodology was further extended by the covalent modification of the h-BN nanosheets with polym...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Applied Physics Letters
سال: 2021
ISSN: ['1520-8842', '0003-6951', '1077-3118']
DOI: https://doi.org/10.1063/5.0051405